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厦门大学化学化工学院有机化学研究所导师介绍:夏海平

作者:聚创厦大考研网-小厦老师 点击量: 908 发布时间: 2018-08-23 15:12 微信号: H17720740258



  夏海平
  教授、博士生导师
  办公室地址:厦门大学卢嘉锡楼746室
  电话:(0592)2184520 (办公室)
  传真:(0592)2186628
  电子邮箱:hpxia@xmu.edu.cn
  课题组网站: http://hpxia.xmu.edu.cn
  个人简历:
  博士 (厦门大学)
  硕士 (厦门大学)
  学士(厦门大学)
  访问学者(香港科技大学)
  闽江学者特聘教授
  先后获得庆祝中国化学会成立六十周年优秀青年化学奖、教育部“全国高等学校优秀骨干教师” 、教育部首届“新世纪优秀人才支持计划”、国家杰出青年科学基金、2013年度“中国高等学校十大科技进展”、中国化学会第七届“黄耀曾金属有机化学奖”。
  研究兴趣:
  金属杂芳香体系构筑方法学及其应用研究,分离膜和膜分离技术。
  近期主要代表论著:
  (23) C. Zhu, S. Li, M. Luo, X. Zhou, Y. Niu, M. Lin, J. Zhu, Z. Cao, X. Lu, T. Wen, Z. Xie, P.Schleyer, H. Xia, Stabilization of anti-aromatic and strained five-membered rings with a transition metal. Nature Chemistry 2013, 5, 698-703.
  (22) Q. Zhuo, J. Lin, Y. Hua, X. Zhou, Y. Shao, S. Chen, Z. Chen, J. Zhu, H. Zhang, H. Xia, Multiyne chains chelating osmium via three metalcarbon σ bonds, Nature Communications 2017, 8, 1912.
  (21) C. Zhu, C. Yang, Y. Wang, G. Lin, Y, Yang, X. Wang, J. Zhu, X. Chen, X. Lu, G. Liu, H. Xia, CCCCC pentadentate chelates with planar M?bius aromaticity and unique properties. Science Advances 2016, 2, e1601031.
  (20) H. Xu, Y. Xu, X. Pang, Y. He, J. Jung, H. Xia, Z. Lin, A general route to nanocrystal kebabs periodically assembled on stretched flexible polymer shish. Science Advances 2015, 1, e1500025.
  (19) C. Zhu, M. Luo, Q. Zhu, J. Zhu, P. v. R. Schleyer, I. Judy, C. Wu, X. Lu, H. Xia, Planar M?bius aromatic pentalenes incorporating 16 and 18 valence electron osmiums. Nature Communications 2014, 5, 3265.
  (18) X.-Y. Cao, Q. Zhao, Z. Lin, H. Xia, The Chemistry of Aromatic Osmacycles. Accounts of Chemical Research 2014, 47, 341-354.
  (17) C. Zhu, J. Zhu, X. Zhou, Q. Zhu, Y. Yang,T. Wen, H. Xia, Isolation of an Eleven-Atom Polydentate Carbon-Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem. Int. Ed. 2018, 57, 3154-3157.
  (16) M. Luo, L. Long, H. Zhang, Y. Yang, Y. Hua, G. Liu, Zh. Lin, H. Xia, Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc. 2017, 139, 1822-1825.
  (15) R. Li, Z. Lu, Y. Cai, F. Jiang, C. Tang, Z. Chen, J. Zheng, J. Pi, R. Zhang, J. Liu, Z. Chen, Y. Yang, J. Shi, W. Hong, H. Xia, Switching of Charge Transport Pathways via Delocalization Changes in Single-Molecule Metallacycles Junctions, J. Am. Chem. Soc. 2017, 139, 14344-14347.
  (14) C. Zhu, J. Wu, S. Li, Y. Yang, J. Zhu, X. Lu, H. Xia, Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings, Angew. Chem. Int. Ed. 2017, 56, 9067-9071.
  (13) C. Zhu, Y. Yang, M. Luo, C. Yang, J. Wu, L. Chen, G. Liu, T. Wen, J. Zhu, H. Xia, Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics. Angew. Chem., Int. Ed. 2015, 54, 6181-6185. (Cover Paper)
  (12) C. Zhu, Y. Yang, J. Wu, M. Luo, J. Fan, J. Zhu, H. Xia, Five-Membered Cyclic Metal Carbyne: Synthesis of Osmapentalynesby the Reactions of Osmapentalene with Allene, Alkyne, and Alkene. Angew. Chem., Int. Ed. 2015, 54, 7295-7298.
  (11) H. Xu, X. Pang, Y. He, M. He, J. Jung, H. Xia, Z. Lin, An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic-Inorganic Nanocomposites. Angew. Chem., Int. Ed. 2015, 54, 4636-4640. (Inside Cover)
  (10) C. Zhu, X. Zhou, H. Xing, K. An, J. Zhu, H. Xia, σ-Aromaticity in an Unsaturated Ring: Osmapentalene Derivatives Containing a Metallacyclopropene Unit. Angew. Chem., Int. Ed. 2015, 54, 3102-3106.
  (9) C. Zhu, Q. Zhu, J. Fan, J. Zhu, X. He, X.-Y. Cao, H. Xia, A metal-bridged tricyclic aromatic system: synthesis of osmium polycyclic aromatic complexes. Angew. Chem. Int. Ed. 2014, 53, 6232-6236.
  (8) T. Wang, J. Zhu, F. Han, C. Zhou, H. Chen, H. Zhang, H. Xia, Synthesis of Five-Membered Osmacycloallenes and Conversion into Six-Membered Osmacycloallenes. Angew. Chem. Int. Ed. 2013, 52, 13361-13364.
  (7) T. Wang, H. Zhang, F. Han, L. Long, Z. Lin, H. Xia, Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization. Angew. Chem. Int. Ed. 2013, 52, 9251-9255.
  (6) Y. Niu, F. Han, Q. Zhang, T. Xie, L. Lu, S. Li, H. Xia, Off/on fluorescent chemosensors for organotin halides based on binuclear ruthenium complexes. Angew. Chem. Int. Ed. 2013, 52, 5599-5603.
  (5) T. Wang, H. Zhang, F. Han, R. Lin, Z. Lin, H. Xia, Synthesis and Characterization of a Metallapyridyne Complex. Angew. Chem. Int. Ed. 2012, 51, 9838-9841.
  (4) Q. Zhao, L. Gong, C. Xu, J. Zhu, X. He, H. Xia, Stable Isoosmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem. Int. Ed. 2011, 50, 1354-1358.
  (3) B. Liu, H. Wang, H. Xie, B. Zeng, J. Chen, J. Tao, T. B. Wen, Z. Cao, H. Xia, Osmapyridine and osmapyridinium from a formal [4+2] cycloaddition reaction, Angew. Chem. Int. Ed. 2009, 48, 5430-5434. (VIP and Frontispiece Paper)
  (2) T. Wang, S. Li, H. Zhang, R. Lin, F. Han, Y. Lin, T. B. Wen, H. Xia, Annulation of Metallabenzenes: From osmabenzene to osmabenzothiazole to osmabenzoxazole, Angew. Chem. Int. Ed. 2009, 48, 6453-6456.
  (1) B. Liu, H. Xie, H. Wang, L. Wu, Q. Zhao, J. Chen, T. B. Wen, Z. Cao, H. Xia, Selective synthesis of osmanaphthalene and osmanaphthalyne by intramolecular C-H activation, Angew. Chem. Int. Ed. 2009, 48, 5461-5464.
  典型产物骨架如下:

   



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